Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Identifieur interne : 000016 ( France/Analysis ); précédent : 000015; suivant : 000017Bis[tris(phenanthroline-κ2N,N′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate
Auteurs : Assia Hajsalem [Tunisie] ; Sameh Aoun [France] ; Aurelien Planchat [France] ; Mohamed Rzaigui [Tunisie] ; Samah Akriche Toumi [Tunisie]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2014.
Abstract
In the title hydrated salt, [Co(C12H8N2)3]2[PVW11O40]·2H2O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO4 group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co2+ ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN6 octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the
Url:
DOI: 10.1107/S160053681400484X
PubMed: 24826091
PubMed Central: 3998553
Affiliations:
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PMC:3998553Le document en format XML
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′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate</title>
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′)cobalt(II)] undecatungsto(VI)vanado(V)phosphate dihydrate</title>
<author><name sortKey="Hajsalem, Assia" sort="Hajsalem, Assia" uniqKey="Hajsalem A" first="Assia" last="Hajsalem">Assia Hajsalem</name>
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<front><div type="abstract" xml:lang="en"><p>In the title hydrated salt, [Co(C<sub>12</sub>
H<sub>8</sub>
N<sub>2</sub>
)<sub>3</sub>
]<sub>2</sub>
[PVW<sub>11</sub>
O<sub>40</sub>
]·2H<sub>2</sub>
O, the complete Kegggin ion is generated by crystallographic inversion symmetry, which imposes statistical disorder on the O atoms of its central PO<sub>4</sub>
group. The V atom is statistically disordered over all the metal sites of the anion. In the cation, the Co<sup>2+</sup>
ion is coordinated by three bidentate 1,10-phenanthroline (phen) ligands, generating a distorted CoN<sub>6</sub>
octahedron. Possible very weak intramolecular C—H⋯π interactions occur in the cation. In the crystal, the components are linked by O—H⋯O and C—H⋯O interactions, building a three-dimensional network featuring one-dimensional voids along the <italic>c</italic>
-axis direction.</p>
</div>
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